Effect of Reducing Metals on Preparation of Niobium Nitride Powder from Niobium Chloride (V)
نویسندگان
چکیده
منابع مشابه
Synthesis and Characterization of a Niobium Nitride Precursor and Niobium Nitride Powder
Anodic dissolution of Nb foil in an electrolyte solution containing liquid NH3 and NH4Br produces an insoluble precursor that can be calcined to yield phase-pure NbN. Infrared spectroscopy is consistent with a precursor having the general formula NbXn(NH2)5-npNH3. By changing the calcination conditions, the phase of the resulting NbN powder can be varied. For example, calcining in pure Ar yield...
متن کاملMixed amido/imido/guanidinato complexes of niobium: potential precursors for MOCVD of niobium nitride thin films.
Novel mixed amido/imido/guanidinato complexes of niobium are reported. The complexes were synthesized by insertion of two equivalents of di-isopropylcarbodiimide (i-Pr-cdi) or bis-cyclohexylcarbodiimide (Cy-cdi) respectively, into the niobium-amido bonds of [Nb(NR(2))(3)(N-t-Bu)] (, R = Me; , R = Et) starting out from [NbCl(3)(N-t-Bu)(py)(2)] and the respective LiNR(2) reagent (py = pyridine). ...
متن کاملPreparation of ingots of uranium-niobium alloy
A study was made of the preparation of a uranium 10 w/o niobium alloy by the bomb reduction of a suitable form of niobium and uranium tetrafluoride with calcium. A compound with a probable formula of Na2NbOF5 proved to be most satisfactory as the source of niobium. High yields and good metal-slag separations were obtained. Chemical analysis and density determinations showed the composition to b...
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چکیده ندارد.
15 صفحه اولNiobium Powder Synthesized by Calciothermic Reduction of Niobium Hydroxide for Use in Capacitors
Metallic niobium powder was produced for applications in electric capacitors via calciothermic reduction of niobium hydroxide in molten CaCl2. Sub-micrometer spherical metallic particles with coral-like morphologies reflected the particle size of the starting oxide powder. A fine powder was obtained from the mixtures of niobium hydroxide and CaO or Ca(OH)2, respectively. Sintered pellets of the...
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ژورنال
عنوان ژورنال: Journal of the Ceramic Association, Japan
سال: 1985
ISSN: 1884-2127,0009-0255
DOI: 10.2109/jcersj1950.93.1084_750